Synthesis of thermally stable SBT and SBS/SBT intergrowth zeolites

نویسندگان

چکیده

Stabilizing large pores Zeolites with very cages, such as zeolite Y, are rare but extremely useful in processing the hydrocarbons petroleum. Lee et al. report a route for preparing thermally stable forms of large-cage phosphate-based molecular sieves UCSB-6 and UCSB-10 (see Perspective by Xie). They used mainly sodium cesium ions inorganic structure-directing agents, along an organic molecule, their charge-density mismatch approach. These zeolites were diesel-cracking catalysts at 600°C. Science , abi7208, this issue p. 104 ; see also abj1834, 28

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

On the rotational intergrowth of hierarchical FAU/EMT zeolites.

A structural study of a hierarchical zeolite X, which is similar to the one first synthesized by Inayat et al.,12 was performed using transmission electron microscopy imaging and diffraction. Evidence is provided, by comparison to simulations, that this material is an intergrowth of FAU and EMT and a conceptual model is presented for the growth of the FAU material with a small fraction of EMT i...

متن کامل

An Alternative Method for Synthesis of Thermally Stable Aromatic Polyesters Containing Schiff Base Unites

In this paper, an efficient method for synthesis of aromatic polyesters containing schiff base units is described by preparation of two polyesters. These polyesters have been prepared by the reaction of terephthaloyl dichloride on Schiff bases derived from p-hydroxybenzyldehyde and 4,4-diamino diphenyl ether, 4,4-diamino diphenyl methane. The Polymers were characterized by IR, CHNS, thermal...

متن کامل

Direct synthesis of hydrothermally stable Ge-IWR zeolites.

The poor hydrothermal stability of germanosilicate zeolites greatly retards their industrial application. Herein, we present a direct synthesis of Ge-containing IWR zeolites with outstanding hydrothermal stability. A simple quaternary ammonium cation, diethyldimethylammonium, was used as the structure-directing agent for the first time. The structure and chemical composition of the framework wa...

متن کامل

Design and synthesis of a thermally stable organic electride.

An electride has been synthesized that is stable to auto-decomposition at room temperature. The key was the theoretically directed synthesis of a per-aza analogue of cryptand[2.2.2] in which each of the linking arms contains a piperazine ring. This complexant was designed to provide strong complexation of Na+ via pre-organization of a "crypt" that contains eight nonreducible tertiary amine nitr...

متن کامل

synthesis of sulfides from alcohols and thiols in solvent-freeconditions and deoxygenation of sulfoxides

کاتالیست یک سنتز جدید برای تیواترها توصیف شده است. واکنش الکل ها با آریل، هتروآریل و آلکیل تیو ل ها درحضور 1،3،5- تری آزو- 2،4،6- تری فسفرین-2،2،4،4،6،6 هگزاکلراید ((tapc به عنوان یک کاتالیست موُثر، بازده های خوب تا عالی از تیواترها را حاصل می کند. علاوه براین، واکنش تحت شرایط بدون فلز و بدون حلال پیش می رود، بنابراین یک مکمل جالب برای روش های شناخته شده سنتز تیواترها ارائه می دهد. یک مکانیسم ا...

15 صفحه اول

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Science

سال: 2021

ISSN: ['2797-0744', '2797-1031']

DOI: https://doi.org/10.1126/science.abi7208